Novel titanium complexes of a multidentate dicarbollide ligand. Synthesis and structural characterization of a constrained geometry complex.

نویسندگان

  • Young-Joo Lee
  • Jong-Dae Lee
  • Jaejung Ko
  • Sang-Hern Kim
  • Sang Ook Kang
چکیده

The multidentate dicarbollide ligand nido-7,8-(NMe2CH2)2-7,8-C2B9H11 has been prepared, structurally characterized, and employed in the preparation of the novel mono- and trimetallic titanium complexes [eta5:eta1-(NMe2CH2)C2B9H9CH2NMe2]Ti(NMe2)2 and [eta5:eta1-[(NMe2CH2)C2B9H9CH2NMe2]Ti(NMe2)]2-mu3-O-Ti(NMe2)2.

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عنوان ژورنال:
  • Chemical communications

دوره 12  شماره 

صفحات  -

تاریخ انتشار 2003